Nano-/microplastics (NP) is a human-made emerging contaminant with worldwide occurrence. The small size (below one micrometer), the different chemical nature and the persistence make NP to potential hazards with suspect probability of tissue penetration and inflammation or as accumulator for toxins. A strategy to stop the spill of novel NP is the remediation from waste water or rivers as prominent distributors. We have developed core–shell superparamagnetic iron oxide nanoparticles (SPIONs) that attract NP and glue them to larger agglomerates which then can be removed from water by applying an external magnetic field. The shell molecules provide two interaction motifs towards NP. The tuned surface potential of the functionalized SPIONs attract complementary charged NP efficiently and the n-alkyl chain is dedicated to preferential interaction towards organic NP rather than inorganic particles. Structural analytics and molecular dynamics simulation support the proposed concept. Systematic remediation experiments with different NP (chemical structures, sizes and mixtures), from different waters – including river water – and with different SPION core materials indicate a universal validity of the concept, with bestremediation performance for mixed NP. We suggest a method for broadband remediation of various NP with simple materials and processes, which both have the potential to be up-scaled.
This paper characterizes the fungal and bacterial colonizers of 5 types of plastic films (High-Density Polyethylene, Low-Density Polyethylene, Polypropylene, Polystyrene, and Polyethylene Terephthalate) throughout a 242-day incubation in the south-eastern Mediterranean and relates them to the chemical changes observed on the surface of the samples via ATR-FTIR. Neither bacterial nor fungal community structures were related[…]
This paper provides insights into the sustainable alternatives that can replace conventional plastic mulches, such as biodegradable mulches made from natural fibers and biopolymers. The microscopic and FTIR analyses conducted during the study showed the degradation of the fibers from the mulches during the exposure time to a certain extent. The nonwoven mulches provide higher[…]
This paper investigates the degradation of biodegradable polybutylene adipate terephthalate/polylactic acid (PBAT/PLA) and traditional polyethylene (PE) plastic under two typical abiotic conditions: ultraviolet (UV) irradiation and mechanical abrasion (MA) for up to nine months. The quantitative analysis of the degradation products was carried out using membrane filtration and total organic carbon determination (MF-TOCD). The results[…]
This paper identifies technological innovation, policy formulation, advocacy and sensitization, and bioremediation as some of the approaches that are currently used for the mitigation of plastic pollution in Nigeria. This chapter also highlights the need to encourage, enhance, and disseminate scientific research on mitigating the harmful effects of plastic pollution in Nigeria. It concluded with[…]
This review provides insights into the sources of microplastics, the ecotoxicity of microplastics, and the impact microplastics have on aquatic and marine life, management, and bioremediation of microplastics. Policies and strategies adopted by the government to combat microplastic pollution are also discussed in this review. Microplastics tend to accumulate in many aquatic systems, contaminate them,[…]