The surge in nano/microplastics (NPs/MPs) through myriad daily products released in the aqueous environment highlights the importance of the urgent development of mitigation techniques. The study has assessed the performance of iron-modified biochar pyrolyzed at two different temperatures, i.e., 550 °C (FB-550) and 850 °C (FB-850), with magnetic extractability for the easy and prompt removal of NPs of varying size and surface functionality. NP1 (1000 nm, carboxyl), NP2 (1000 nm, amine), and NP3 (30 nm, carboxyl) were subjected to batch experiments with the composites. Rapid elimination of all the NPs (<10 min) from the water system using robust magnetic-composites was observed. A higher-order of reaction kinetics (n > 2) was found through the general order model, and a good fit for Sips isotherm suggests ultrafast NPs removal and heterogeneous nature of the composite surface. Maximum removal capacities for NP1 (225.11 mg/g), and NP3 (206.46 mg/g) were obtained using FB-850, whereas FB-550 showed higher removal of NP2 (290.20 mg/g). The influence of solution pH on the sorption of NPs was limited with significant variation in zeta potential, suggesting the probability of surface complexation of NPs. The spectroscopic analysis of reaction mixture showed the disappearance of COO− peak, generation of FeOOH stretching, and shift in Fe-O band, confirming the involvement of surface complexation in the sorption process. Minimal impact of environmental parameters, reaction spontaneity, and efficient removal of NPs in complex aqueous matrices justify the composites’ environmental applicability. No-iron release and excellent reusability of the utilized adsorbents support the large-scale applicability of the composites.
The paper studies the microplastic abundances and characteristics in the Southern Jiangsu Canal to reveal the effect of riverside cities on microplastics in river water. The results show that the microplastic abundance in the water body of the South Jiangsu Canal ranges from 3.41 to 19.07 particles L−1, with an average of 9.59 ± 3.95[…]
This paper reveals the status of microplastic pollution in paddy soil with long-term mulching. The study investigates the distribution and weathering characteristics of filmy microplastics in a mulched paddy field (non-mulched, four years of mulched, and ten years of continuous mulched soil were investigated) in Southwest China. The filmy microplastics accumulated annually in the plough[…]
The paper reviews advancements in polymer technologies that aim to improve the efficiency of recycling and upcycling plastic waste. Increasing the rate of recycling and upcycling is critical for addressing the issues caused by plastic pollution, and, at the same time, overcoming the technical limitations on the same. The research emphasises the need to develop[…]
The study analyses the current advancements in the behavioural differences between MPs and NPs in urban waters. Analytical challenges, fate, interactions with surrounding pollutants, and eco-impacts of MPs and NPs are similarly discussed in this paper. It has been highlighted in the study that the characterization and fate studies of NPs are more challenging as[…]
The study investigates scientifically evidence-based policy initiatives for targeting plastic pollution. The issue of plastic pollution is complex and still related to several uncertainties, which implies that policy initiatives must allow for flexibility and ongoing evaluations to adjust to the evolving knowledge generation. It is also important that the scientific community provide the needed research[…]