The surge in nano/microplastics (NPs/MPs) through myriad daily products released in the aqueous environment highlights the importance of the urgent development of mitigation techniques. The study has assessed the performance of iron-modified biochar pyrolysed at two different temperatures, i.e., 550°C (FB-550) and 850°C (FB-850), with magnetic extractability for the easy and prompt removal of NPs of varying size and surface functionality. NP1 (1000 nm, carboxyl), NP2 (1000 nm, amine), and NP3 (30 nm, carboxyl) were subjected to batch experiments with the composites. Rapid elimination of all the NPs (<10 min) from the water system using robust magnetic composites was observed. A higher order of reaction kinetics (n > 2) was found through the general order model, and a good fit for the Sips isotherm suggests ultrafast NPs removal and the heterogeneous nature of the composite surface. Maximum removal capacities for NP1 (225.11 mg/g) and NP3 (206.46 mg/g) were obtained using FB-850, whereas FB-550 showed higher removal of NP2 (290.20 mg/g). The influence of solution pH on the sorption of NPs was limited with significant variation in zeta potential, suggesting the probability of surface complexation of NPs. The spectroscopic analysis of the reaction mixture showed the disappearance of the COO− peak, the generation of FeOOH stretching, and the shift in the Fe-O band, confirming the involvement of surface complexation in the sorption process. Minimal impact of environmental parameters, reaction spontaneity, and efficient removal of NPs in complex aqueous matrices justifies the composites’ environmental applicability. No-iron release and excellent reusability of the utilised adsorbents support the large-scale applicability of the composites.
The Ocean Plastics Charter aims to bring together leading countries, sub-national governments, businesses, and civil society organisations to commit to a more resource-efficient and sustainable approach to keep plastics in the economy and out of the environment. With this charter, it aims to transition to a more sustainable and resource-efficient method of managing plastics. Through[…]
These regulations are intended to promote sustainable development, food security, and the sustainable management of fishing activities in Palau’s waters. They also intend to create economic returns, employment generation, and export earnings from the sustainable harvesting of tuna and tuna-like species by encouraging the development of domestic fishing industries and a local tuna market. These[…]
This subchapter E of Title 40 of the Code of Federal Regulations outlines the pesticide programs, including registration and classification procedures, policies, special review procedures, standards, labelling requirements, packaging requirements, data requirements, and good laboratory practice standards. It also covers state registration of pesticide products, rules of practice governing hearings under the federal Insecticide, Fungicide,[…]
The Plastics Roadmap aims to decrease littering and other environmental harm brought on by plastics, prevent needless use, enhance plastic recycling, and replace traditional polymers derived from fossil fuels combined with various substances and liquids. To guarantee more focus on sustainable product development, reuse, product recyclability, and the growing usage of recovered plastics, these objectives[…]
The regulations aim to enhance aquaculture pollution prevention and control, protect aquatic ecosystems, ensure product quality and safety, and promote sustainable development. They consist of 24 articles divided into four sections: general provisions, delimitation of prohibited areas, pollution prevention and control, and environmental monitoring and supervision of fishery waters.